Commercialization and implementation of the energy- and recourse-saving technologies at the enterprises of Saint-Petersburg Polymer Cluster Alena V. Dynina KP Plant, LLC International innovation week The Netherlands

The newest nanotechnologies along with computer-information technologies and biotechnologies are the ground of scientific and technological revolution of the XXIst century comparable with transformations in techniques and in the society caused by the most influential discoveries of the XXth century. And these technologies sometimes can surpass transformations in scales The newest nanotechnologies along with computer-information technologies and biotechnologies are the ground of scientific and technological revolution of the XXIst century comparable with transformations in techniques and in the society caused by the most influential discoveries of the XXth century. And these technologies sometimes can surpass transformations in scales Nanotechnologies may become a powerful instrument of the Russian technological complex integration in the international market of Hi-Tech and provide competitiveness of domestic products Nanotechnologies may become a powerful instrument of the Russian technological complex integration in the international market of Hi-Tech and provide competitiveness of domestic products Nanotechnologies Revolution

Nanomaterials and pulping technologies Nanomaterials is the materials which contain the structural elements with geometrical dimensions less then 100 nanometers and which have absolutely new properties, operational and functional characteristics

The 7 th International Conference on nanotechnologies (Visbaden, 2004) Nano bodies, nano fibers - Nano bodies, nano fibers - Nano pipes and fullerenes - Nanoporous structures - Nanodispersions - Nanostructured surfaces and films - Nano crystal materials According to the Conference the following nanomaterials were underlined:

Structures on base of carbon *Graphene model in the form of 2D hexagonal latitude * Fullerene model *Mono wall carbon nano pipe model *Poly walls carbon nano pipe model

Upwards technology The technology " upwards " is coming down to nanoscale object production by means of particular atoms and molecules construction. In almost every technology of atoms collecting from separate atoms condensation is reasonable * Condensation (from lat. condenso – to compact, to thicken) is a substance transfer from gas to liquid or solid caused by cooling or compression Within condensation of nanoelements production there is a need to dissolve atoms from their micro body. Dissolving can be conducted by means of thermal or laser heating of micro body. Dissolved atoms should be transferred to lower temperature zone where condensation will start. On base of condensation fullerenes, carbon pipes, nano clusters, and nano elements of different scales can be produced.

Downwards technology The "downwards" technology is based on scales reduction of bodies by mechanical or other processing up to the nanometers scale production. For example nano elements can be produced by macro scale material milling in special mill Structure by lithography

NANOCOVERINGS - Coverings combining polymer layers and nano elements of chrystal (automobile mirrors, bathroom mirrors, glasses of digital cameras, sport glasses etc.); - Coverings on base of sol/jelly –technologies (can be applied to wind screens to make them more sustained to scratches); - Dirt- and humidity resisting color for outwalls; - Multilayer paper for inkjet printers. *Nanocovering for automobile mirror. On the picture above the left side of mirror id processed, on the lower picture – the right side

Nanotechnologies in medicine Ag nano elements antibacterial - Ag nano elements antibacterial For instance antibacterial dressings with nano elements of Ag. Nano elements kill even those micro organisms who are not sensitive to standard antiseptics. Tube wheels coating antisepticise clothes during washing. The German scientists introduced ions of Ag in clothes and bed-clothes which are recommended to use by people with eczema and other skin diseases. -creation of up-molecular medicinal capsules Using these capsules high dozes of medicines can be transferred in the source of disease minimizing by-effects

Use of technologies of PPU and UHMWPE spraying. Warm loses reduction owing to heat- and hydro-insulation. Suah coatings application leads to energy consumption reduction on 435 гКал/ч (323,64 гКал/мес). *According to the SPbSUFE payback period in energy-saving sphere - 4,8 years POLYMER COATING OF ROOF PLACES AND SUBBASEMENTS

POLYMER NANO COATINGS AND DE-ICING MATERIALS IMPLEMENTATION De-icing and nano materials coatings of buildings 'roofs by colors of Pigment and SPbSTI (TU) Use of UHMWPE sheets vice galvanized iron De-icing and nano materials coatings of buildings 'roofs by colors of Pigment and SPbSTI (TU) Use of UHMWPE sheets vice galvanized iron Roof spaces covering by heat-insulation materials (PPU), produced by LLC Institute of polymers: «foamed glass», «isotherm» Roof spaces covering by heat-insulation materials (PPU), produced by LLC Institute of polymers: «foamed glass», «isotherm» Buildings visors de-icing covering on base of UHMWPE. Technology is produced by SPbSU, CRDI Prometi and LLC Institute of polymers Subbasement coating (hydro isolation) by composite materials on base of UHMWPE. Technologies are produced by chemical faculty of SPbSU, LLC Institute of polymers. Pre- preg siding by Ioffe Institute. Powdered colors spraying of plumbing ware Heat- and hydro isolation of subbasements by PPU. Technology is produced by LLC Institute of polymers Heat isolation of heating tubes Energy-saving lightening devices and management system UHMWPE coverings of metal weeper

утеплитель из ППУ Воздух T 0 °C Теплый воздух T 25 °C Снег Антиобледенительное покрытие Водосточный гребень Наноантиобледенительн ое покрытие Теплый воздух от стен и подвала Снежный гранулят ARRANGEMENTS COMPLEX FOR ICING PREVENTION

PPU COATING

LIST OF SAMPLES IN NATURE TESTING LAB п/пType of coating п/п Type of coating 1СВМПЭ газопламенным методом12 Органосиликатная композиция (шаровая) без грунтовки 2Композиция на основе СВМПЭ газопламенным методом13 Органосиликатная композиция (зеленая) с нанодобавками 3Листы с СВМПЭ 1х1 м электростатический метод14 Органосиликатная композиция на грунтовке (вариант 2)36 часов 4Листы с порошковым окрашиванием 1х1 м15 Органосиликатная композиция на грунтовке (вариант 1)36 часов 5Порошковые краски с нанодобавками16 Органосиликатная композиция на грунтовке (вариант 1) 72 часа 6Краска «Пигмент»17 Органосиликатная композиция на грунтовке (вариант 2)72 часа 7Краска «Пигмент» с нанодобавками18Грунтовый слой + эпоксидная смола 8Органосиликатная композиция (зеленая) без грунтовки19 Композиция с СВМПЭ с грунтовкой и чистый СВМПЭ 9 Органосиликатная композиция (красно – коричневая) без грунтовки 20Чистый лист СВМЭТолщина 30 ммТолщина 2 мм 10 Композиция с СВМПЭ с грунтовкой и СВМПЭ+ гидроокись алюминия 21 Листы 1х1 м препрега и 6 листов 3м (длина)х1,2 м (ширина) c нанесеннной композицией 11Композиция СВМПЭ с грунтовкой и СВМПЭ+ тальк22Композиция с СВМПЭ с нанодобавкой

FIRST TESTING RESULTS This is the samples of organo silicate compounds with nano elements

FIRST TESTING RESULTS

UHMWPE SHEETS Thin 30 mmThin 2 mm

Samples of coatings by color OS with pre-coating

SAMPLES OF COATINGS AND FIRST RESULTS ПокрытиеХарактеристика покрытия Натурные наблюдения ПокрытиеХарактеристика покрытия Натурные наблюдения СВМПЭ (газопламенное напыление) Шероховатая поверхность, толщина неравномерная. Материал при нанесении выгорает Наледь хорошо скатывается Первый слой грунтовка(вариант 1), второй слой шаровая органосиликатная композиция Разводы темного цвета, небольшая шероховатость на отдельных участках листа Снег легко счищается с кровли Органосиликатная композиция (шаровая) наномодифицированн ая Поверхность ровная, гладкая Наледь хорошо скатывается (лучше, чем на образцах I-1, I- 2, I-3, I-4), но при отбивке материал с кровельного железа отстает Первый слой грунтовка(вариант 2), второй слой шаровая органосиликатная композиция Покрытие ровное, гладкое Снег легко счищается с кровли Органосиликатная композиция (красно- коричневая),наномодиф ицированная Поверхность ровная, гладкая Наледь хорошо скатывается (лучше, чем на образцах I-1, I- 2, I-3, I-4), но при отбивке материал с кровельного железа отстает Композиция на основе СВМПЭ с нанодобавками Шероховатая поверхность, толщина неравномерная, материал при нанесении выгорает Снег легко счищается с кровли Органосиликатная композиция (зеленая)наномодифици рованная Поверхность ровная, гладкая Наледь хорошо скатывается (лучше, чем на образцах I-1, I- 2, I-3, I-4), но при отбивке материал с кровельного железа отстает Лист СВМПЭ 2.7 ×1.2 м толщиной 30 мм Поверхность ровная, гладкая Наледь хорошо скатывается, остаются небольшие области наледи Композиция на основе СВМПЭ Шероховатая поверхность, толщина неравномерная, материал при нанесении полностью не расплавляется. Часть наледи остается на поверхности, плохо скатывается Лист СВМПЭ 2.7 ×1.2 м толщиной 2 мм Поверхность ровная, гладкая Наледь хорошо скатывается

ANTI-ICING COATINGS Polymer anti-icing coatings on base of UHMWPE can decide a number of problems: Polymer anti-icing coatings on base of UHMWPE can decide a number of problems: Owing to liquidity index of UHMWPE during heating material closes existing doors and holes and pot probe hems; Owing to liquidity index of UHMWPE during heating material closes existing doors and holes and pot probe hems; High level of resistance protect the surface of the roof from the mechanical influence; High level of resistance protect the surface of the roof from the mechanical influence; UHMWPE elasticity index helps to preserve proof during thermal enlargements in winter and summer season; UHMWPE elasticity index helps to preserve proof during thermal enlargements in winter and summer season; High adhesion of anti-icing coatings on base of UHMWPE protects the surface from corrosion and thus polymer coatings exploitation period can be more than 10 years. High adhesion of anti-icing coatings on base of UHMWPE protects the surface from corrosion and thus polymer coatings exploitation period can be more than 10 years.

THANK YOU! Alena Dynina Polymer cluster