1 UNIT-8 SCIENCE & TECHNOLOGY OF NANOMATERIALS

2 S. No. Module Lectur e No. PPT Slide No. 1 Introduction. Nano science and Nano technology Nano technology L Fabrication of Nano materials Fabrication of Nano materials L Physical and chemical Properties of nano materials. L Carbon Nano tubes & Applications. L UNIT INDEX

3 APPLIED PHYSICS CODE : 07A1BS05 CODE : 07A1BS05 I B.TECH I B.TECH CSE, IT, ECE & EEE CSE, IT, ECE & EEE UNIT-8 UNIT-8 NO. OF SLIDES :41 NO. OF SLIDES :41

4 SCIENCE & TECHNOLOGY OF NANO MATERIALS Nanoscience can be defined as the study of phenomena and manipulation of materials at atomic, molecular and macromolecular scales, where properties differ significantly from those at a larger scale. Lecture-1

5 Nano means A nanometre (nm) is one thousand millionth of a metre ( i.e. 10-9). Atoms are extremely small and the diameter of a single atom can vary from Nano means A nanometre (nm) is one thousand millionth of a metre ( i.e. 10-9). Atoms are extremely small and the diameter of a single atom can vary from 0.1 to 0.5 nm depending on the type of the element. For example, one carbon atom is approximately 0.15 nm in diameter. The radius of the atom can be considered as half the distance between neighbouring atoms when they are present in the solid phase. 0.1 to 0.5 nm depending on the type of the element. For example, one carbon atom is approximately 0.15 nm in diameter. The radius of the atom can be considered as half the distance between neighbouring atoms when they are present in the solid phase.

6 Nanotechnology Nanotechnology can be defined as the design, characterization, production and application of structures, devices and systems by controlling shape and size at the nanometre scale. Nanotechnology can be defined as the design, characterization, production and application of structures, devices and systems by controlling shape and size at the nanometre scale. Lecture-1Lecture-1 Lecture-1Lecture-1 Lecture-2

7 All materials are composed of grains, which in turn comprise of many atoms. Depending on the size, these grains may be visible or invisible to the naked eye. Conventional materials have grains of size varying from hundreds of microns to centimeters. Any bulk material we take, its size can be expressed in three dimensions. All materials are composed of grains, which in turn comprise of many atoms. Depending on the size, these grains may be visible or invisible to the naked eye. Conventional materials have grains of size varying from hundreds of microns to centimeters. Any bulk material we take, its size can be expressed in three dimensions.

8 Any planar material we take, its area can be expressed in two dimensions. Any linear material we take, its length can be expressed in one dimension. Nanomaterials could be defined as those materials which have structured components with size less than 100 nm at least in one dimension. Any planar material we take, its area can be expressed in two dimensions. Any linear material we take, its length can be expressed in one dimension. Nanomaterials could be defined as those materials which have structured components with size less than 100 nm at least in one dimension.

9 Materials that are nanoscale in one dimension (and are extended in the other two dimensions) are layers, such as thin films or surface coatings. Materials that are nanoscale in one dimension (and are extended in the other two dimensions) are layers, such as thin films or surface coatings. Materials that are nanoscale in two dimensions (and are extended in one dimension) include nanowires and nanotubes. Materials that are nanoscale in two dimensions (and are extended in one dimension) include nanowires and nanotubes.

10 Materials that are nanoscale in three dimensions are particles, for example precipitates, colloids and quantum dots (tiny particles of semiconductor materials). Nanocrystalline materials, made up of nanometre-sized grains, also fall into this category. Materials that are nanoscale in three dimensions are particles, for example precipitates, colloids and quantum dots (tiny particles of semiconductor materials). Nanocrystalline materials, made up of nanometre-sized grains, also fall into this category.

11 Production of Nanomaterials Production of Nanomaterials Materials can be produced that are nanoscale in one dimension (for example, very thin surface coatings), in two dimensions (for example, nanowires and nanotubes) or in all three dimensions (for example, nanoparticles). Materials can be produced that are nanoscale in one dimension (for example, very thin surface coatings), in two dimensions (for example, nanowires and nanotubes) or in all three dimensions (for example, nanoparticles). Lecture-3

12 Nanomaterials can be synthesised by 'top down' techniques, producing very small structures from larger pieces of material. One way of doing this is mechanical crushing of solid into fine nanopowder (ball milling). Nanomaterials can be synthesised by 'top down' techniques, producing very small structures from larger pieces of material. One way of doing this is mechanical crushing of solid into fine nanopowder (ball milling).

13 Nanomaterials may also be synthesised by 'bottom up' techniques, atom by atom or molecule by molecule. One way of doing this is to allow the atoms or molecules arrange themselves into a structure due to their natural properties e.g. Crystals grown. Nanomaterials may also be synthesised by 'bottom up' techniques, atom by atom or molecule by molecule. One way of doing this is to allow the atoms or molecules arrange themselves into a structure due to their natural properties e.g. Crystals grown.

14 Preparation of Nanomaterials: Preparation of Nanomaterials: Now there are many known methods to produce nanomaterials. Now there are many known methods to produce nanomaterials. i) Plasma arcing i) Plasma arcing ii) Chemical Vapour Deposition (CVD) ii) Chemical Vapour Deposition (CVD) iii) Sol-Gels iii) Sol-Gels iv) Electrodeposition iv) Electrodeposition v) Ball Milling v) Ball Milling

15 Nano materials have a relatively larger surface area when compared to Nano materials have a relatively larger surface area when compared to the same volume (or mass) of the material produced in a larger form. Let us consider a sphere of radius "r", the same volume (or mass) of the material produced in a larger form. Let us consider a sphere of radius "r", Lecture-4

16 Quantum confinement effects: We know how energy bands are formed. When atoms are isolated the energy levels are discrete. When very large number of atoms are closely packed to form a solid, the energy levels split and form bands. Nanomaterials represent intermediate stage. We know how energy bands are formed. When atoms are isolated the energy levels are discrete. When very large number of atoms are closely packed to form a solid, the energy levels split and form bands. Nanomaterials represent intermediate stage.

17 We have studied the problems of particles in a potential well as well as in a potential box. When the dimensions of such wells or boxes are of the order of de Broglie wavelength of electrons or mean free path of electrons (i.e. within few tens of nanometre), energy levels of electrons change. This effect is called Quantum confinement. We have studied the problems of particles in a potential well as well as in a potential box. When the dimensions of such wells or boxes are of the order of de Broglie wavelength of electrons or mean free path of electrons (i.e. within few tens of nanometre), energy levels of electrons change. This effect is called Quantum confinement.

18 When the material is in sufficiently small size typically 10 nanometers or less, organization of energy levels into which electrons can climb or fall change. Specifically, the phenomenon results from electrons and holes being squeezed into a dimension that approaches a critrical quantum measurement, called the "exciton Bohr radius." These can affect the optical, electrical and magnetic behaviour of materials, particularly as the structure or particle size approaches the smaller end of the nanoscale. When the material is in sufficiently small size typically 10 nanometers or less, organization of energy levels into which electrons can climb or fall change. Specifically, the phenomenon results from electrons and holes being squeezed into a dimension that approaches a critrical quantum measurement, called the "exciton Bohr radius." These can affect the optical, electrical and magnetic behaviour of materials, particularly as the structure or particle size approaches the smaller end of the nanoscale.

19 Carbon Nanotubes (CNTs) Carbon Nanotubes (CNTs) Carbon nanotubes were first observed by Sumio Iijima in So far we know only three forms of carbon, namely diamond, graphite, and amorphous carbon. Now we come to know that there is a whole family of other forms of carbon known as Carbon nanotubes, which are related to graphite. Carbon nanotubes were first observed by Sumio Iijima in So far we know only three forms of carbon, namely diamond, graphite, and amorphous carbon. Now we come to know that there is a whole family of other forms of carbon known as Carbon nanotubes, which are related to graphite. Lecture-5

20 The molecular structure of graphite is one atom- thick a planar network of interconnected hexagonal rings of carbon atoms. In conventional graphite, the sheets of carbon are stacked on top of one another. They can easily slide over each other. That is why graphite is not hard, and can be used as a lubricant. When graphite sheets are rolled into a cylinder and their edges joined, they form carbon nanotubes. i.e. Carbon nanotubes are extended tubes of rolled graphite sheets. The molecular structure of graphite is one atom- thick a planar network of interconnected hexagonal rings of carbon atoms. In conventional graphite, the sheets of carbon are stacked on top of one another. They can easily slide over each other. That is why graphite is not hard, and can be used as a lubricant. When graphite sheets are rolled into a cylinder and their edges joined, they form carbon nanotubes. i.e. Carbon nanotubes are extended tubes of rolled graphite sheets.

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22 Carbon nanotubes have assumed an important role because of their novel chemical and physical properties. They are Carbon nanotubes have assumed an important role because of their novel chemical and physical properties. They are mechanically very strong (their Young's modulus is over 1 terapascal, making CNTs as stiff as diamond), mechanically very strong (their Young's modulus is over 1 terapascal, making CNTs as stiff as diamond), flexible (about their axis), and can conduct electricity extremely-well. flexible (about their axis), and can conduct electricity extremely-well.

23 Applications of Nanomaterials :- Applications of Nanomaterials :- Nanoparticles are "the small particles with a big future. Because of their extremely small particle size, they have extremely large specific surface area. Hence they are chemically very active. They are stronger and more ductile. They have electronic states quite different from those of bulk. Nanoparticles are "the small particles with a big future. Because of their extremely small particle size, they have extremely large specific surface area. Hence they are chemically very active. They are stronger and more ductile. They have electronic states quite different from those of bulk.

24 In dispersed state nanoparticles are used as fillers, paints, magenetic recording media, ferrofluids, drugs, phosphors, rocket propellant, fuel addittives etc. In dispersed state nanoparticles are used as fillers, paints, magenetic recording media, ferrofluids, drugs, phosphors, rocket propellant, fuel addittives etc. ln consolidate state nanoparticles are used as catalysits, electodes of solar cells and fuel cells, sensors, adsorbents, synthetic bone, self cleaning glass etc. ln consolidate state nanoparticles are used as catalysits, electodes of solar cells and fuel cells, sensors, adsorbents, synthetic bone, self cleaning glass etc.

25 In ordered assembly form nanoparticles are used as quantum electronic devices, photonic crystals, DNA chips, biosensors etc. In ordered assembly form nanoparticles are used as quantum electronic devices, photonic crystals, DNA chips, biosensors etc. In very dense phase nanoparticles are used in synthesis of flexible/dense ceramics and insulators, harder metals etc. In very dense phase nanoparticles are used in synthesis of flexible/dense ceramics and insulators, harder metals etc.

26 i) Materials Technology: Magnets made of nanocrystailine yttrium- samarium_cobalt grains posess unusual mangentic properties due to their extremery large grain interface area. High coercivity can be obtained because magnetization flips cannot easily propagate past the grain boundaries. This could lead to applications in motors, analytical instruments like magnetic resonance imaging (MRI). Magnets made of nanocrystailine yttrium- samarium_cobalt grains posess unusual mangentic properties due to their extremery large grain interface area. High coercivity can be obtained because magnetization flips cannot easily propagate past the grain boundaries. This could lead to applications in motors, analytical instruments like magnetic resonance imaging (MRI).

27 ceramics are hard, brittre and difficurt to machine. However, with a reduction in grain size to the nanoscare, ceramic ductility can be increased.zirconia, normally a hard, brittle ceramic, has even been rendered superplastic (for example, able to be deformed up to 3oo% of its original length) ceramics are hard, brittre and difficurt to machine. However, with a reduction in grain size to the nanoscare, ceramic ductility can be increased.zirconia, normally a hard, brittle ceramic, has even been rendered superplastic (for example, able to be deformed up to 3oo% of its original length)

28 Nanocrystalrine ceramics, such as silicon nitride and silicon carbide, have been used in such automotive applications as high-strength springs, ball bearings and valve lifters, because they can be-easily formed and machined, as well as exhibiting excellent chemical and high temperature properties. They are also used as components in high-temperature furnaces. Nanocrystalrine ceramics, such as silicon nitride and silicon carbide, have been used in such automotive applications as high-strength springs, ball bearings and valve lifters, because they can be-easily formed and machined, as well as exhibiting excellent chemical and high temperature properties. They are also used as components in high-temperature furnaces.

29 Nanosized titanium diozide and zinc oxide are currently used in sun -screens. They absorb and reflect ultraviolet (uv) rays and yet are transparent to visible light. Nanosized titanium diozide and zinc oxide are currently used in sun -screens. They absorb and reflect ultraviolet (uv) rays and yet are transparent to visible light. Nanosized iron oxide is present in some lipsticks as a pigment. Nanosized iron oxide is present in some lipsticks as a pigment.

30 An important use of nanoparticles and nanotubes in composites. Composite materials combine one or more separate components and are designed to exhibit overall the best properties of each component. Currently, carbon fibres and bundles of multi-walled CNTs are used in composites having potential long-term applications. An important use of nanoparticles and nanotubes in composites. Composite materials combine one or more separate components and are designed to exhibit overall the best properties of each component. Currently, carbon fibres and bundles of multi-walled CNTs are used in composites having potential long-term applications. carbon nanoparticles act as fillers in a matrix; for example, they are used as a filler to reinforce car tyres. carbon nanoparticles act as fillers in a matrix; for example, they are used as a filler to reinforce car tyres.

31 Clay particle based composites-containing plastics and nano-sized flakes of clay are also finding applications such as use in car bumpers. Clay particle based composites-containing plastics and nano-sized flakes of clay are also finding applications such as use in car bumpers. Recently developed applications include the self- cleaning windows. Nano coating of highly activated titanium dioxide is highly hydrophobic (water repellent) and antibacterial. Coatings based on nanoparticulate oxides catalytically destroy chemical agents Recently developed applications include the self- cleaning windows. Nano coating of highly activated titanium dioxide is highly hydrophobic (water repellent) and antibacterial. Coatings based on nanoparticulate oxides catalytically destroy chemical agents

32 Wear and scratch-resistant hard coatings are significantly improved by nanoscale intermediate layers (or multilayers) between are hard outer layer and the substrate material. The intermediate layers give good bonding and graded matching of elastic and thermal properties, thus improving adhesion Wear and scratch-resistant hard coatings are significantly improved by nanoscale intermediate layers (or multilayers) between are hard outer layer and the substrate material. The intermediate layers give good bonding and graded matching of elastic and thermal properties, thus improving adhesion

33 Improved control of porosity at the nanoscale has important applications. A range of enhanced textiles, such as breathable, waterproof and stain resistant fabrics, have been enabled by this technique in variety of polymers and inorganics. Improved control of porosity at the nanoscale has important applications. A range of enhanced textiles, such as breathable, waterproof and stain resistant fabrics, have been enabled by this technique in variety of polymers and inorganics.

34 Other novel, and more long-term, applications for nanoparticles lie in paints that change colour in response to change in temperature or chemical environment, or paints that have reduced infrared absorptivity and so reduce heat loss. Other novel, and more long-term, applications for nanoparticles lie in paints that change colour in response to change in temperature or chemical environment, or paints that have reduced infrared absorptivity and so reduce heat loss.

35 Nanoparticles react with pollutants in soil and groundwater and transform them into harmless compounds. Iron nanoparticles transform chlorinated hydrocarbons (which are carcinogens) into less harmful end products in groundwater. Iron nanoparticles could be used to transform heavy metals such as lead and mercury from bio available forms into insoluble forms. Nanoparticles react with pollutants in soil and groundwater and transform them into harmless compounds. Iron nanoparticles transform chlorinated hydrocarbons (which are carcinogens) into less harmful end products in groundwater. Iron nanoparticles could be used to transform heavy metals such as lead and mercury from bio available forms into insoluble forms.

36 Information Technology Nanoscale-fabricated magnetic materials also have applications in data storage. If the area required to record one piece of information can be shrunk in the nanoscale (and can be written and read reliably), the storage capacity of the disk can be improved dramatically. The devices on computer chips which operate using flows of electrons could use the magnetic properties oi these electrons, called spin, with numerous advantages. Nanoscale-fabricated magnetic materials also have applications in data storage. If the area required to record one piece of information can be shrunk in the nanoscale (and can be written and read reliably), the storage capacity of the disk can be improved dramatically. The devices on computer chips which operate using flows of electrons could use the magnetic properties oi these electrons, called spin, with numerous advantages.

37 Coatings with thickness controlled at the nano or atomic scale have been used in opto electronic devices or in catalytically active and chemically functionalized Surfaces. Coatings with thickness controlled at the nano or atomic scale have been used in opto electronic devices or in catalytically active and chemically functionalized Surfaces. CNTs are beinginvestigated for lowvoltagefield emission displays;their strength, sharpness, conductivity and inertness make them potentially very efficient and long-lasting emitters. CNTs are beinginvestigated for lowvoltagefield emission displays;their strength, sharpness, conductivity and inertness make them potentially very efficient and long-lasting emitters.

38 Nanocrystalline zincselenide, zinc sulphide and lead telluride telluride synthesized by sol-gel techniques are candidates for the next generation of light emitting phosphors, they will have huge market for large area, high brightness, flat-panel displays ( as used in television screen and computer monitors) Nanocrystalline zincselenide, zinc sulphide and lead telluride telluride synthesized by sol-gel techniques are candidates for the next generation of light emitting phosphors, they will have huge market for large area, high brightness, flat-panel displays ( as used in television screen and computer monitors)

39 Nanoparticles are used for information storage Nanoparticles are used for information storage Quantum electronic devices have started replacing bulky conventional devices. Quantum electronic devices have started replacing bulky conventional devices. Nano dimensional photonic crystals are used in chemical/optical computers. Nano dimensional photonic crystals are used in chemical/optical computers.

40 Biomedicals :- Nanocrystalline zirconium oxide(zirconia) is hard,wear resistant,bio- corrosion resistant and bio-compatible. If therefore presents an attractive alternative material for implants. It and other nanoceramics can also be made used as strong, light aerogels by sol-gel techniques. Nanocrystalline silicon carbide is a candidate material for artificial heart valves primarily because of its low weight, high strength and inertness. Nanocrystalline zirconium oxide(zirconia) is hard,wear resistant,bio- corrosion resistant and bio-compatible. If therefore presents an attractive alternative material for implants. It and other nanoceramics can also be made used as strong, light aerogels by sol-gel techniques. Nanocrystalline silicon carbide is a candidate material for artificial heart valves primarily because of its low weight, high strength and inertness.

41 Contlrolled drug delivery is possible using nanotechnology. Diffusion of medicine through nanoporous polymer reservoir as per the requirement is very useful in controlling the disease. Contlrolled drug delivery is possible using nanotechnology. Diffusion of medicine through nanoporous polymer reservoir as per the requirement is very useful in controlling the disease. Nano strucured ceramics readily interact with bone cells and hence finds application as an implant material Nano strucured ceramics readily interact with bone cells and hence finds application as an implant material